ORGANIC CHEMISTRY II

CHEM-212 Spring 2003

Dr. Paul Schueler
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ORGANIC CHEMISTRY II |
SYLLABUS |
SPRING 2003 |
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Dr. Paul Schueler |
Lecture/Recitation: |
Sec 51, 52: MW 5:30-7:20 PM SC101 |
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Office: SC206 |
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Telephone: XT 8219 |
Laboratory: |
Sec 51: Th 5:30-9:20 PM SC220 |
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email: pschuele@raritanval.edu |
Web page: |
http://www.raritanval.edu/departments/Science/Paul.html |
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Spring 2003 Office Hours: |
Mon 2:30-3:30 PM |
Tues 9:30-10:30 AM |
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Wed 2:30-3:30 PM |
Thurs 1:30-2:30 PM |
Textbook: "Organic Chemistry", John McMurry, 5th Edition,
Brooks/Cole, 2000.
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Class Date |
McMurry Chapter |
Omit Sections |
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1/27, 29 |
13. Nuclear Magnetic Resonance Spectroscopy |
13.6 |
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2/3 |
12. Mass Spectrometry & Infrared Spectroscopy |
12.3, 12.4 |
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2/5, 10 |
14. Conjugated Dienes |
14.10-14.13 |
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2/12, 17 |
15. Benzene & Aromaticity |
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2/24 |
EXAM I: Chapters 12-15 |
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3/3, 5 |
16. Electrophilic Aromatic Substitution |
16.8, 16.9 |
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3/10, 12 |
17. Alcohols & Phenols |
17.9-17.11 |
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3/24, 26, 31 |
19. Aldehydes & Ketones: Nucleophilic Addition Reactions; 14.10-14.13: Ultraviolet Spectroscopy |
19.13 |
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4/2 |
EXAM II: Chapters 16, 17, 19 |
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4/7 |
20. Carboxylic Acids |
20.8 |
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4/9, 14 |
21. Carboxylic Acid Derivatives |
21.9 |
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4/16 |
22. Carbonyl a-Substitution Reactions |
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4/21, 23, 28 |
23. Carbonyl Condensation Reactions |
23.12, 23.13 |
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4/30 |
EXAM III: Chapters 20-23 |
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5/5, 7 |
25. Biomolecules: Carbohydrates |
25.8, 25.12 |
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5/14 |
FINAL EXAM Chapters 12-17, 19-25 |
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The week of 3/17-3/22 is the Winter vacation break. Please read the material in the textbook before coming to class. Suggested problems will be discussed during the recitation periods. Three exams will be given during the semester, on the dates indicated. In addition, there will be a cumulative Final Exam, tentatively scheduled for May 14. Sample exams will be handed out and discussed prior to the exams. It is very important that you not fall behind in this course! Studying with your classmates, either in study groups or informally, is very helpful. I will be glad to assist you in setting up study groups. Your grade for the course will be determined as follows:
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Exams (15% each): |
45% |
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Final Exam : |
30% |
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Laboratory : |
25% |
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ORGANIC CHEMISTRY II |
LABORATORY SCHEDULE |
SPRING 2003 |
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Dr. Paul Schueler |
Sec 51:
Thursday 5:30-9:20 PM SC220 |
Textbook: "Organic Experiments", Eighth Edition, L. F. Fieser
and K. L. Williamson, Houghton Mifflin Co., 1998.
Laboratory Schedule
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Laboratory Date |
Experiment (Fieser and Williamson) |
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1/28 |
1/30 |
Check-in; NMR Spectroscopy |
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2/4 |
2/6 |
6. Steam Distillation (part 3); 12. Infrared Spectroscopy |
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2/11 |
2/13 |
49. Diels-Alder Reaction (parts 1, 2, & 3) |
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2/18 |
2/20 |
Cancelled (snow) |
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2/25 |
2/27 |
28. Nitration of Methyl Benzoate |
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3/4 |
3/6 |
32. The Friedel-Crafts Reaction (parts 2 & 3) |
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3/11 |
3/13 |
26. Sodium Borohydride Reduction of 2-Methylcyclohexanone |
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3/25 |
3/27 |
38. Grignard Synthesis of Triphenylmethanol (parts 1, 2, 4) |
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4/1 |
4/3 |
70. Qualitative Organic Analysis: Solubility and Physical Properties |
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4/8 |
4/10 |
70. Qualitative Organic Analysis: Identification of Unknowns |
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4/15 |
4/17 |
70. Qualitative Organic Analysis: Identification of Unknowns |
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4/22 |
4/24 |
70. Qualitative Organic Analysis: Identification of Unknowns |
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4/29 |
5/1 |
37. Dibenzalacetone by the Aldol Condensation |
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5/6 |
5/8 |
Make-up and Check-out* |
You must read the Experiment before coming to the laboratory. Your laboratory
grade (which constitutes 25% of the overall course grade), will be determined by
your results, your lab notebook, and your general performance in the
laboratory.
Assigned Problems in McMurry
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Chapter 12: |
3, 7, 9-12, 17, 19, 23,28, 31-37, 39-41, 46-49. |
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Chapter 13: |
3, 4, 6-8, 12-20, 22, 23, 25, 29-31, 33-42, 44-54, 61, 65, 66. |
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Chapter 14: |
1-6, 9-11, 15, 16, 20-26, 29, 31-34, 37, 38, 40, 43, 51. |
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Chapter 15: |
1-4, 6-11, 17-27, 29-45. |
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Chapter 16: |
1-16, 18-23, 27-36, 39, 40, 42-51, 56, 57, 63, 65, 66, 70. |
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Chapter 17: |
1-14, 17-19, 24-38, 40, 41, 43-46, 49, 50, 54-63. |
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Chapter 19: |
1-11, 13-16, 19, 20, 25-32, 34-40, 42-44, 49-51, 57-62, 64-66. |
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Chapter 20: |
1-7, 9-14, 17-26, 28-30, 32-39, 41, 42, 44-49. |
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Chapter 21: |
1-6, 8-22, 24-32, 35-49, 29, 52, 59, 63-65, 67-71. |
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Chapter 22: |
1-8, 10-16, 20-24, 26-35, 40-45. |
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Chapter 23: |
1-5, 7-16, 25-40, 43-46, 51, 52, 56. |
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Chapter 24: |
1-10, 13, 16-19, 23-33, 37, 38, 42, 43, 46-48, 52, 55, 63-65. |
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Chapter 25: |
1-7, 9-13, 15-18, 24, 29-38, 45, 49, 51. |