ORGANIC CHEMISTRY II

nmr1.gif (3105 bytes)

 

CHEM-212 Spring 2003

chlorophyll.gif (6111 bytes)

Dr. Paul Schueler

 

 ORGANIC CHEMISTRY II

 SYLLABUS

 SPRING 2003

 

Dr. Paul Schueler

 Lecture/Recitation:

Sec 51, 52: MW 5:30-7:20 PM SC101

Office: SC206

 

 

Telephone: XT 8219

Laboratory:

Sec 51: Th  5:30-9:20 PM SC220
Sec 52: T    1:30-5:20 PM SC220

email: pschuele@raritanval.edu

Web page:

http://www.raritanval.edu/departments/Science/Paul.html

Spring 2003 Office Hours:

Mon 2:30-3:30 PM

Tues 9:30-10:30 AM

 

Wed 2:30-3:30 PM

Thurs 1:30-2:30 PM


Textbook: "Organic Chemistry", John McMurry, 5th Edition, Brooks/Cole, 2000.

 Class Date

McMurry Chapter

 Omit Sections

 

 

 

1/27, 29

13. Nuclear Magnetic Resonance Spectroscopy

13.6

2/3

12. Mass Spectrometry & Infrared Spectroscopy

12.3, 12.4

2/5, 10

14. Conjugated Dienes

14.10-14.13

2/12, 17

15. Benzene & Aromaticity

 

 

 

 

2/24

EXAM I: Chapters 12-15

 

 

 

 

3/3, 5

16. Electrophilic Aromatic Substitution

16.8, 16.9

3/10, 12

17. Alcohols & Phenols

17.9-17.11

3/24, 26, 31

19. Aldehydes & Ketones: Nucleophilic Addition Reactions;

14.10-14.13: Ultraviolet Spectroscopy

19.13

 

 

 

4/2

EXAM II: Chapters 16, 17, 19

 

 

 

 

4/7

20. Carboxylic Acids

20.8 

4/9, 14

21. Carboxylic Acid Derivatives

21.9

4/16

22. Carbonyl a-Substitution Reactions

 

4/21, 23, 28

23. Carbonyl Condensation Reactions

23.12, 23.13

 

 

 

4/30

 EXAM III: Chapters 20-23

 

 

 

 

5/5, 7

25. Biomolecules: Carbohydrates

25.8, 25.12

 

 

 

5/14

FINAL EXAM Chapters 12-17, 19-25

 

The week of 3/17-3/22 is the Winter vacation break. Please read the material in the textbook before coming to class. Suggested problems will be discussed during the recitation periods. Three exams will be given during the semester, on the dates indicated. In addition, there will be a cumulative Final Exam, tentatively scheduled for May 14. Sample exams will be handed out and discussed prior to the exams. It is very important that you not fall behind in this course! Studying with your classmates, either in study groups or informally, is very helpful. I will be glad to assist you in setting up study groups. Your grade for the course will be determined as follows:

 Exams (15% each):

 45%

 Final Exam :

 30%

 Laboratory :

 25%

 


 

 

ORGANIC CHEMISTRY II

  LABORATORY SCHEDULE

 SPRING 2003

 

 Dr. Paul Schueler

Sec 51: Thursday 5:30-9:20 PM SC220
Sec 52: Tuesday  1:30-5:20 PM SC220


Textbook: "Organic Experiments", Eighth Edition, L. F. Fieser and K. L. Williamson, Houghton Mifflin Co., 1998.

Laboratory Schedule

 Laboratory Date
Sec 52      Sec 51

 Experiment (Fieser and Williamson)

 1/28

1/30

Check-in; NMR Spectroscopy

2/4

2/6

6. Steam Distillation (part 3); 12. Infrared Spectroscopy

2/11

2/13

49. Diels-Alder Reaction (parts 1, 2, & 3)

2/18

2/20

Cancelled (snow)

2/25

2/27

28. Nitration of Methyl Benzoate

3/4

3/6

32. The Friedel-Crafts Reaction (parts 2 & 3)

3/11

3/13

26. Sodium Borohydride Reduction of 2-Methylcyclohexanone

3/25

3/27

38. Grignard Synthesis of Triphenylmethanol (parts 1, 2, 4)

4/1

4/3

70. Qualitative Organic Analysis: Solubility and Physical Properties

4/8

4/10

70. Qualitative Organic Analysis: Identification of Unknowns

4/15

4/17

70. Qualitative Organic Analysis: Identification of Unknowns

4/22

4/24

70. Qualitative Organic Analysis: Identification of Unknowns

4/29

5/1

37. Dibenzalacetone by the Aldol Condensation

5/6

5/8

Make-up and Check-out*



You must read the Experiment before coming to the laboratory. Your laboratory grade (which constitutes 25% of the overall course grade), will be determined by your results, your lab notebook, and your general performance in the laboratory. 


 

Assigned Problems in McMurry

Chapter 12:

3, 7, 9-12, 17, 19, 23,28, 31-37, 39-41, 46-49.

Chapter 13:

3, 4, 6-8, 12-20, 22, 23, 25, 29-31, 33-42, 44-54, 61, 65, 66.

Chapter 14:

1-6, 9-11, 15, 16, 20-26, 29, 31-34, 37, 38, 40, 43, 51.

Chapter 15:

1-4, 6-11, 17-27, 29-45.

Chapter 16:

1-16, 18-23, 27-36, 39, 40, 42-51, 56, 57, 63, 65, 66, 70.

Chapter 17:

1-14, 17-19, 24-38, 40, 41, 43-46, 49, 50, 54-63.

Chapter 19:

1-11, 13-16, 19, 20, 25-32, 34-40, 42-44, 49-51, 57-62, 64-66.

Chapter 20:

1-7, 9-14, 17-26, 28-30, 32-39, 41, 42, 44-49.

Chapter 21:

1-6, 8-22, 24-32, 35-49, 29, 52, 59, 63-65, 67-71.

Chapter 22:

1-8, 10-16, 20-24, 26-35, 40-45.

Chapter 23:

1-5, 7-16, 25-40, 43-46, 51, 52, 56.

Chapter 24:

1-10, 13, 16-19, 23-33, 37, 38, 42, 43, 46-48, 52, 55, 63-65.

Chapter 25:

1-7, 9-13, 15-18, 24, 29-38, 45, 49, 51.