ORGANIC CHEMISTRY II

CHEM-212 Spring 2002

Dr. Paul Schueler
| ORGANIC CHEMISTRY II | SYLLABUS |
SPRING 2002 |
| Dr. Paul Schueler | Lecture/Recitation: |
Sec 01: MW 1:25-3:20 PM N329 |
| Office: S226 | ||
| Telephone: XT 8219 | Laboratory: |
Sec 01: Th 1:30-5:20 PM S353 |
| email: pschuele@raritanval.edu | Web page: |
http://www.raritanval.edu/departments/Science/Paul.html |
| Spring 2002 Office Hours: | Mon 3:30-4:30 PM | Tues 11:00-12:00 PM |
| Wed 11:00-12:00 PM | Thurs 12:30-1:30 PM |
Textbook: "Organic
Chemistry", John McMurry, 5th Edition, Brooks/Cole, 2000.
| Class Date | McMurry Chapter |
Omit Sections |
| 1/23, 28 | 12. Mass Spectrometry I & Infrared Spectroscopy | |
| 1/30, 2/4 | 14. Conjugated Dienes & Ultraviolet Spectroscopy | |
| 2/6, 11 | 15. Benzene & Aromaticity | |
| 2/13, 18, 20 | 16. Electrophilic Aromatic Substitution | 16.9 |
| 2/25 | EXAM I: Chapters 12, 14, 15, 16 |
|
| 2/27, 3/4 | 17. Alcohols & Phenols | 17.9, 11 |
| 3/6 | 18. Ethers & Epoxides | 18.4, 6, 9, 11 |
| 3/18, 20 | 19. Aldehydes & Ketones: Nucleophilic Addition Reactions | 19.13, 14 |
| 3/25 | EXAM II: Chapters 17, 18, 19 |
|
| 3/27 | 20. Carboxylic Acids |
|
| 4/1, 3 | 21. Carboxylic Acid Derivatives | 21.9 |
| 4/8 | 22. Carbonyl a-Substitution Reactions |
|
| 4/10, 15 | 23. Carbonyl Condensation Reactions | 23.12, 13 |
| 4/17 | EXAM III: Chapters 20-23 |
|
| 4/22 | 24. Amines | 24.9 |
| 4/24, 29 | 25. Biomolecules: Carbohydrates | 25.8 |
| 5/1, 6 | 26. Biomolecules: Amino Acids, Peptides,& Proteins |
|
| 5/13 (tentative) | FINAL EXAM Chapters 12, 14-26 |
The week of 3/11-3/16 is the Winter vacation break. Please read the material in the textbook before coming to class. Suggested problems will be discussed during the recitation periods. Three exams will be given during the semester, on the dates indicated. In addition, there will be a cumulative Final Exam, tentatively scheduled for May 13. Sample exams will be handed out and discussed prior to the exams. It is very important that you not fall behind in this course! Studying with your classmates, either in study groups or informally, is very helpful. I will be glad to assist you in setting up study groups. Your grade for the course will be determined as follows:
| Exams (15% each): | 45% |
| Final Exam : | 30% |
| Laboratory : | 25% |
| ORGANIC CHEMISTRY II | LABORATORY SCHEDULE |
SPRING 2002 |
| Dr. Paul Schueler | Sec 01: Thursday 1:25-5:20 PM S353 |
Textbook: "Organic Experiments", Eighth Edition, L. F. Fieser
and K. L. Williamson, Houghton Mifflin Co., 1998.
Laboratory Schedule
Laboratory Date |
Experiment (Fieser and Williamson) |
| 1/24 | Check-in; 6. Steam Distillation (part 3); 12. Infrared Spectroscopy |
| 1/31 | 49. Diels-Alder Reaction (parts 1, 2, & 3) |
| 2/7 | 28. Nitration of Methyl Benzoate |
| 2/14 | 32. The Friedel-Crafts Reaction (parts 2 & 3) |
| 2/21 | 26. Sodium Borohydride Reduction of 2-Methylcyclohexanone |
| 2/28 | 38. Grignard Synthesis of Triphenylmethanol (parts 1, 2, 4) |
| 3/7 | 55. Nitric Acid Oxidation: Preparation of Benzil from Benzoin; Diphenylquinoxaline |
| 3/21 | 70. Qualitative Organic Analysis: Solubility and Physical Properties |
| 3/28 | 70. Qualitative Organic Analysis: Identification of Unknowns |
| 4/4 | 70. Qualitative Organic Analysis: Identification of Unknowns |
| 4/11 | 70. Qualitative Organic Analysis: Identification of Unknowns |
| 4/18 | Make-up and Check-out* |
* The lab schedule ends early this semester because of the completion of
the Science Building and the necessity to accommodate the renovation of the
science labs in the South Building.
You must read the Experiment before coming to the laboratory. Your laboratory grade (which
constitutes 25% of the overall course grade), will be determined by your results, your lab
notebook, and your general performance in the laboratory.
Assigned Problems in McMurry
| Chapter 12: | 3, 7, 9-12, 17, 19, 23,28, 31-37, 39-41, 46-49. |
| Chapter 14: | 1-6, 9-11, 15, 16, 20-26, 29, 31-34, 37, 38, 40, 43, 51. |
| Chapter 15: | 1-4, 6-11, 17-27, 29-45. |
| Chapter 16: | 1-16, 18-23, 27-36, 39, 40, 42-51, 56, 57, 63, 65, 66, 70. |
| Chapter 17: | 1-14, 17-19, 24-38, 40, 41, 43-46, 49, 50, 54-63. |
| Chapter 18: | 1, 3-8, 11-13, 18, 25, 26(a-e), 27, 28, 32-35, 38, 42, 50, 52, 54. |
| Chapter 19: | 1-11, 13-16, 19, 20, 25-32, 34-40, 42-44, 49-51, 57-62, 64-66. |
| Chapter 20: | 1-7, 9-14, 17-26, 28-30, 32-39, 41, 42, 44-49. |
| Chapter 21: | 1-6, 8-22, 24-32, 35-49, 29, 52, 59, 63-65, 67-71. |
| Chapter 22: | 1-8, 10-16, 20-24, 26-35, 40-45. |
| Chapter 23: | 1-5, 7-16, 25-40, 43-46, 51, 52, 56. |
| Chapter 24: | 1-10, 13, 16-19, 23-33, 37, 38, 42, 43, 46-48, 52, 55, 63-65. |
| Chapter 25: | 1-7, 9-13, 15-18, 24, 29-38, 45, 49, 51. |
| Chapter 26: | 1-5, 7-11, 14, 17-19, 22, 26, 29-31, 34-38, 40, 49, 52, 55, 59-61. |