| ORGANIC CHEMISTRY II | SYLLABUS |
SPRING 1999 |
| Dr. Paul Schueler | Lecture/Recitation: |
Sec 01: MW 1:20-3:15 PM A24 |
| Office: S304 | Sec 51: MW 5:20-7:15 PM N333 | |
| Telephone: XT 8219 | Laboratory: |
Sec 01: T 1:20-5:10 PM S353 |
| email:pschuele@exchange.raritanval.edu | Sec 51: Th 5:30-9:20 PM S353 |
Textbook: "Organic Chemistry", L. G. Wade, Jr., 3rd Edition, Prentice Hall,
1995.
| Class Date | Wade Chapter |
Omit Sections |
| 1/20,25 | 11. Infrared Spectroscopy and Mass Spectrometry | 11-15 |
| 27, 2/1, 3 | 12. Nuclear Magnetic Resonance Spectroscopy | |
| 2/8, 10 | 15. Conjugated Systems, Orbital Symmetry, & UV Spectroscopy | |
| 2/15, 17 | 16. Aromatic Compounds | |
| 2/22 | EXAM I: Chapters 11, 12, 15, 16 |
|
| 2/24, 3/1 | 17. Reactions of Aromatic Compounds | 17-12, 13 |
| 3/3, 8, 10 | 18. Ketones and Aldehydes | 18-8, 9 |
| 3/22, 24 | 19. Amines | 19-11D, 15, 16, 24, 25 |
| 3/29 | EXAM II: Chapters 17, 18, 19 |
|
| 3/31, 4/5 | 20. Carboxylic Acids | 20-7D, 15, 16 |
| 4/7, 12 | 21. Carboxylic Acid Derivatives | 21-15 |
| 4/14, 19 | 22. Additions & Condensations of Enols & Enolates | 22-12 |
| 4/21 | EXAM III: Chapters 20-22 |
|
| 4/26, 28 | 23. Carbohydrates & NucleicAcids | 23-12 - 23-17 |
| 5/3, 5, 10 | 24. Amino Acids, Peptides,& Proteins | 24-10, 11 |
| 5/17 (tentative) | FINAL EXAM Chapters 11, 12, 15-24 |
The week of 3/15-3/20 is the Winter vacation break. Please read the material in the textbook before coming to class. Suggested problems will be discussed during the recitation periods. Three exams will be given during the semester, on the dates indicated. In addition, there will be a cumulative Final Exam, tentatively scheduled for May 17. Sample exams will be handed out and discussed prior to the exams. It is very important that you not fall behind in this course! Studying with your classmates, either in study groups or informally, is very helpful. I will be glad to assist you in setting up study groups. Your grade for the course will be determined as follows:
| Exams (15% each): | 45% |
| Final Exam : | 30% |
| Laboratory : | 25% |
| ORGANIC CHEMISTRY II | LABORATORY SCHEDULE |
SPRING 1999 |
| Dr. Paul Schueler | 01: Tuesday 1:20-5:15 PM S353 |
| Dr. Barbara Kostis | 51: Thursday 5:20-9:15 PM S353 |
Textbook: "Organic Experiments", Eighth Edition, L. F. Fieser
and K. L. Williamson, Houghton Mifflin Co., 1998.
Laboratory Schedule
Laboratory Date Sec 01 Sec 51 |
Experiment (Fieser and Williamson) | |
| 1/26 | 1/28 | Check-in; 13. NMR Spectroscopy |
| 2/2 | 2/4 | 49. Diels-Alder Reaction (parts 1, 2, & 3) |
| 2/9 | 2/11 | 28. Nitration of Methyl Benzoate |
| 2/16 | 2/18 | 32. The Friedel-Crafts Reaction (parts 2 & 3) |
| 2/23 | 2/25 | 22. Oxidation: Cyclohexanol to Cyclohexanone; Cyclohexanone to Adipic Acid |
| 3/2 | 3/4 | 26. Sodium Borohydride Reduction of 2-Methylcyclohexanone |
| 3/9 | 3/11 | 55. Nitric Acid Oxidation: Preparation of Benzil from Benzoin; Diphenylquinoxaline |
| 3/23 | 3/25 | 45. The Sandmeyer Reaction: 4-Chlorotoluene |
| 3/30 | 4/1 | 70. Qualitative Organic Analysis: Solubility and Physical Properties |
| 4/6 | 4/8 | 70. Qualitative Organic Analysis: Identification of Unknowns |
| 4/13 | 4/15 | 70. Qualitative Organic Analysis: Identification of Unknowns |
| 4/20 | 4/22 | 70. Qualitative Organic Analysis: Identification of Unknowns |
| 4/27 | 4/29 | 37. Dibenzalacetone by the Aldol Condensation |
| 5/4 | 5/6 | Make-up and Check-out |
You must read the Experiment before coming to the laboratory. Your laboratory grade (which
constitutes 25% of the overall course grade), will be determined by your results, your lab
notebook, and your general performance in the laboratory.
Assigned Problems in Wade
| Chapter 11: | 2-11, 14-16, 19-24. |
| Chapter 12: | 1-10, 18-40, 42, 44, 46. |
| Chapter 15: | 1-3, 5-11, 13-15, 17, 20, 21, 23, 24, 26, 28-32, 35 |
| Chapter 16: | 2-4, 7-14, 16, 18-20, 22, 25-34, 36-40, 43. |
| Chapter 17: | 1, 2, 4-12, 14-22, 30-38, 43-50, 53, 54, 56, 58. |
| Chapter 18: | 1, 2, 5, 6, 8-23, 25-28, 30, 32-37, 54, 56-59. |
| Chapter 19: | 1-3, 5-7, 10-14, 17-20, 25-30, 32-34, 37, 39, 40, 43, 44, 46-54, 57-59. |
| Chapter 20: | 1-4, 7, 8, 11-19, 25-33, 35-44. |
| Chapter 21: | 1-10, 12-15, 17-22, 24, 27, 29, 32-35, 38-40, 42-53, 56, 58-60, 64-67. |
| Chapter 22: | 1-14, 16-31, 36-55, 58-61, 63-81. |
| Chapter 23: | 1-3, 5-10, 14-16, 18, 20-26, 29, 39, 42, 44-49, 52-54, 56, 58, 64, 69-73. |
| Chapter 24 | 1-5, 8-10, 14, 15, 18, 19, 23, 24, 32-37, 39, 41, 47, 50. |